APPLICATIONS OF MOFs MATERIALS (CuOBA) AS A CATALYST FOR REACTION OF 5’-BROMO-2’-HYDROXIACETOPHENONE AND BENZYL ETHER
Keywords:
MOF material, copper catalyst, C=O coupling reaction
Abstract
The metal organic frameworks material (CuOBA) was synthesized by solvothermal method. The physicochemical characteristics of this solid catalyst were determined by a number of different analytical techniques including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and Fourier transform infrared (FT-IR). The CuOBA was used as a heterogeneous catalyst for the coupling reaction of C=O connection between 5’- bromo - 2’-hydroxiacetophenone and benzyl ether in good conversion. The effects of time, temperature, concentration of reactants, solvents, and mass of catalyst were surveyed. The results revealed that CuOBA is used as a catalyst for organic reactions with conversion of 87%, and the solid catalyst could be recovered six times without a significant degradation in catalytic activity.
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Strategies, Structure Patterns, and Emerging
Properties in the Chemistry of Modular Porous Solids. Acc Chem Res. 1998;31:474–484.
[2] You-Kyong Seo, G H, In Tae Jang, Young
Kyu Hwang, Chul-Ho Jun, Jong-San Chang. Microwave synthesis of hybrid inorganic–organic materials including porous Cu3(BTC)2 from Cu(II)-
trimesate mixture. Microporous and Mesoporous Materials. 2009;119:331–337.
[3] David J Tranchemontagne, José L Mendoza – Cortés,
Michaek O’ Keeffe, Omar M Yaghi. Sencondary
builing units, nets and bonding in the chemistry
of metal – organic frameworks. Chemical Society
Review. 2009;38:1257–1283.
[4] Pichon A, Lazuen-Garay A, James S L. Solvent-free
synthesis of a microporous metal-organic framework.
CrystEngComm. 2006;8:211.
[5] U Mueller, M Schubert, F Teich, H Puetter,
K chierle Arndt, J Pastre. Metal–organic frameworks
prospective industrial applications. J Mater Chem. 2006;16:626–636.
[6] Lê Thành Dũng, Nguyễn Thanh Tùng, Phan Thanh
Sơn Nam. Vật liệu khung cơ kim (mofs): các ứng
dụng từ hấp phụ khí đến xúc tác. Tạp chí Khoa học
và Công nghê. 2012;50(6):751–766.
[7] Jian-Rong Li, Ryan J Kuppler, Hong-Cai Zhou. Selective gas adsorption and separation in metal–organic
frameworks. Chem Soc Rev. 2009;38:1477–1504.
[8] Mohamed Eddaoudi, Hailian Li, O M Yaghi. Highly
Porous and Stable Metal-Organic Frameworks: Structure Design and Sorption Properties. J Am Chem Soc. 2000;122:1391–1397.
[9] Mohamed Eddaoudi, Jaheon Kim, Nathaniel Rosi,
David Vodak, Joseph Wachter, Michael O’Keeffe,
et al. Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in
Methane Storage. Science. 2002;295:469–472.
[10] Li H, Davis C E, Groy T L, Kelley D G, Yaghi O M.
Coordinatively unsaturated metal Centers in the Extended Porous Framework of Zn3(BDC)3.6CH3OH
(BDC=1,4-benzenedicarboxilate). J Am Chem Soc. 1998;120:2186.
[11] Jihye Park, Sang Hoon Han, Satyasheel Sharma,
Sangil Han, Youngmi Shin, Neeraj Kumar Míhra,
et al. Copper-Catalyzed Oxidative C-O Bond Formation of 2-Acyl Phenosand 1,3-Dicarbony; Compounds
with ethers: Direct access to phenol esters and enol
esters. J Org Chem. 2014;79(10):4735–4742.
[12] Thien N Lieu, Ha T T Nguyen, Ngoc D M Tran,
Thanh Truong, Nam T S Phan. O Acetyl Substituted
Phenol Ester Synthesis via Direct Oxidative Esterification Utilizing Ethers as an Acylating Source with
Cu2(dhtp) Metal Organic Framework as a Recyclable
Catalyst. Ind Eng Chem Res. 2016;55:11829–11838.
[13] Haoxi Jiang, Jiali Zhou, Caixia Wang, Yonghui Li,
Yifei Chen, Minhua Zhang. Effect of Co-solvent and
Temperature on the Structures and Properties of CuMOF-74 in Low-temperature NH3-SCR. Ind Eng
Chem Res. 2017;55(13):3542–3550.
[14] ZHANG XiaoFeng, YANG Qian, ZHAO JiongPeng,
HU Tong-Liang, CHANG Ze, BU Xian-He. Three interpenetrated copper(II) coordination polymers based
on a V-shaped ligand: Synthesis, structures, sorption
and magnetic properties. Department of Chemistry,
Nankai University, Tianjin 300071; 2011.
Published
05-March-2019
How to Cite
1.
Nguyen H, Nguyen T. APPLICATIONS OF MOFs MATERIALS (CuOBA) AS A CATALYST FOR REACTION OF 5’-BROMO-2’-HYDROXIACETOPHENONE AND BENZYL ETHER. journal [Internet]. 5Mar.2019 [cited 22Dec.2024];9(33):37-8. Available from: https://journal.tvu.edu.vn/tvujs_old/index.php/journal/article/view/140
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